Formation and C–F bond functionalization of [P,N]-ligated perfluoronickelacyclopentanes
| Autor: | R. Tom Baker, Ilia Korobkov, Kaitie A. Giffin, Lorraine A. Pua |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Substitution reaction Base (chemistry) 010405 organic chemistry Metallacycle 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Surface modification Tetrafluoroethylene Reactivity (chemistry) Physical and Theoretical Chemistry |
| Zdroj: | Polyhedron. 157:458-466 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2018.10.024 |
| Popis: | Detailed herein is the synthesis and characterization of [P,N]-ligated perfluoronickelacyclopentanes based on the bidentate ligand 2-(diphenylphosphino)phenyl-N-phenylaniline [P,NH]. A high-yielding substitution reaction between [P(O-o-tol)3]2Ni(C4F8) and [P,NH] gives the phosphine-amine-coordinated metallacycle [P,NH]Ni(C4F8). Alternatively, [P,NH]Ni(C4F8) is formed upon treatment of Ni[P(O-o-tol)3]4 with one equiv. of [P,NH] followed by tetrafluoroethylene. This product reacts quantitatively with base to give an anionic phosphine-amido-ligated nickelacycle. Reactivity studies of the new [P,NH]- and [P,N−]-ligated perfluoronickelacycles are presented and compared and contrasted with our previously reported [P,S] systems. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect