Synthesis and structures of compounds containing double bonds between the heavier Group VA elements: diphosphenes, diarsenes, phosphaarsenes, and phosphastibenes
| Autor: | Bruce R. Whittlesey, J. G. Lasch, Jan E. Kilduff, Alan H. Cowley, Jerry L. Atwood, Marek Pakulski, William E. Hunter, S. K. Mehrotra, Nicholas C. Norman |
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| Rok vydání: | 1984 |
| Předmět: |
chemistry.chemical_classification
Double bond Stereochemistry Crystal structure Nuclear magnetic resonance spectroscopy Electronic structure Diphosphenes Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Group (periodic table) X-ray crystallography Molecule Physical and Theoretical Chemistry |
| Zdroj: | Inorganic Chemistry. 23:2582-2593 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/ic00185a010 |
| Popis: | Preparation des composes (Me 3 Si) 3 CP=PC(SiMe 3 ) 3 , [2,4,6-(t-Bu) 3 C 6 H 2 ]P=PC(SiMe 3 ) 3 , [2,4,6-(t-Bu) 3 C 6 H 2 ]P=M=H(SiMe 3 ) 2 avec M=P. As et Sb et [2,4,6-(t-Bu) 3 C 6 H 2 ]As=AsCH(SiMe 3 ) 2 . Etude des structures cristallines de trois d'entre eux. Discussion sur la nature de la double liaison a partir des donnees RX et RMN |
| Databáze: | OpenAIRE |
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