Further molecular engineering of diruthenium-(2-anilinopyridinate) alkynyl compounds through ligand design

Autor:	Hong-Ling Han, Tong Ren, Bin Xi, Jie-Wen Ying, Guo-Lin Xu, Antoinette Cordova
Rok vydání:	2008
Předmět:	Stereochemistry Ligand Acetylide Organic Chemistry Biochemistry Medicinal chemistry Molecular engineering Inorganic Chemistry chemistry.chemical_compound Molecular wire chemistry Pyridine Materials Chemistry Physical and Theoretical Chemistry Single crystal
Zdroj:	Journal of Organometallic Chemistry. 693:1656-1663
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2007.11.050
Popis:	A modified ap ligand, 2-(3,5-dimethoxyanilino)pyridine (HDiMeOap) and its diruthenium compounds Ru2(DiMeOap)4Cl (1), Ru2(DiMeOap)4(C CC CSiMe3) (2) and Ru2(DiMeOap)4(C CC CSiMe3)2 (3) were prepared and characterized. New compounds Ru2(MeOap)4(C CC CSiMe3)x (x = 1, 4; 2, 5; MeOap is 2-(3-methoxyanilino)pyridinate) were prepared from the previously reported Ru2(MeOap)4Cl. In addition, two related diruthenium compounds containing ferrocenyl acetylide ligand, Ru2(MeOap)4(C CFc) (6) and Ru2(ap)4(C CC CFc) (7), were synthesized. Molecular structures of compounds 1, 2, 6 and 7 were established using single crystal X-ray diffraction study.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5ca14220ec8228031049f4903239c528 https://doi.org/10.1016/j.jorganchem.2007.11.050 Zobrazit plný text záznamu Full Text from ScienceDirect