ChemInform Abstract: The Interaction of Diazo Compounds with Phosphorylated Systems with S-H, S-S, S-Hal Bonds

Autor: A. S. Ishmuratov, N. A. Torgasheva, B. A. Khaskin
Rok vydání: 1990
Předmět:
Zdroj: ChemInform. 21
ISSN: 0931-7597
Popis: The interactions of phosphorylsulphenylhalides, phosphorylated disulphides, thio- and dithiophosphoric acids with diazo compounds were investigated. It has been shown that these reactions mainly lead to the insertion of methylene groups into S-Hal, S-S, S-H bonds. α-Chloromethyl-phosphorothio- and -dithioates are obtained from the corresponding phosphoryl- and thiophosphorylsulphenyl-chlorides. As for phosphorylsulphenylbromides, the reaction is accompanied by phosphoryl-thiophosphoryl rearrangements
Databáze: OpenAIRE