Formation of the State-Selected CH Radical Beam and its Application to The CH + NO Reaction

Autor:	H. Ohoyama, T. Kasai, M. Takezaki, K Kuwata
Rok vydání:	1995
Předmět:	Chemistry Analytical chemistry Photochemistry Biochemistry Decomposition Atomic and Molecular Physics and Optics law.invention Wavelength chemistry.chemical_compound law Methanol Spectroscopy Beam (structure) Chemiluminescence
Zdroj:	Laser Chemistry. 15:113-121
ISSN:	1476-3516 0278-6273
DOI:	10.1155/1995/97838
Popis:	The CH(X2II) radical beam was produced via the decomposition of methanol by a dc-discharge in a pulsed supersonic beam. The CH radical beam was rotationally state-selected and separated from other discharge products by using an electrostatic hexapole field. The chemiluminescence from the reaction of CH in the |3/2, 3/2, 3/2> state with NO was measured under the crossed beam condition. The wavelength region of the present chemiluminescence confirms no NH(A3II) formation. The formation of HCN(X) and/or OH(X2II) is tentatively proposed.
Databáze:	OpenAIRE
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