Iron atoms redistribution in oxide films of Zr-Fe, Zr-Fe-Cu alloys during corrosion in autoclave at 350°C

Autor:	A. B. Bateev, V. P. Filippov
Rok vydání:	2016
Předmět:	Materials science Inorganic chemistry Zirconium alloy Oxide Intermetallic Iron oxide Hematite Corrosion chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Iron oxide cycle Solid solution
Zdroj:	IOP Conference Series: Materials Science and Engineering. 130:012015
ISSN:	1757-899X 1757-8981
DOI:	10.1088/1757-899x/130/1/012015
Popis:	The data on changes of iron atoms state in the oxide films of binary Zr-1.24 mas.%Fe and ternary Zr-1.39 mas.%Fe-0.60 mas.%Cu zirconium alloys are obtained. Alloys are subjected to corrosion tests under autoclave conditions at 350°C temperature in a steam-water environment under pressure p = 16.8 MPa. In initial specimens of the alloys the iron atoms are in the form of intermetallic compounds. In oxide films the decomposition of intermetallic compounds and formation of new compounds occurs with structural phase distortion. In the oxide films metallic the metallic iron particles α-Fe, iron oxide in the form of hematite α-Fe2O3, solid solutions of iron ions in ZrO2 are formed. The phase composition of the oxide films depends on the alloy composition and changes during the growth process of the oxide film.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5c4ad956e1886f5888ab0abbb5d66d83 https://doi.org/10.1088/1757-899x/130/1/012015 Zobrazit plný text záznamu