A regiospecific synthesis of unsaturated nucleosides, carbohydrates and other olefins

Autor:	Yang Jing-Hua, Zhu Ju-Liang, Liu Mao-Chin, Lin Tai-Shun
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Addition reaction Cyclohexane Hydride Alkene Organic Chemistry Azobisisobutyronitrile Biochemistry Adduct Solvent chemistry.chemical_compound chemistry Drug Discovery Organic chemistry Vicinal
Zdroj:	Tetrahedron Letters. 31:3829-3832
ISSN:	0040-4039
Popis:	Vicinal disubstituted nucleosides, carbohydrates and cyclohexane derivatives with a pair of radical leaving groups, such as chloro, bromo, phenoxythiocarbonyloxy, and imidazolylthiocarbonyloxy groups, have been successfully converted to the corresponding olefins in high yields (60–90%) without observed side products, by reaction with tri-n-butyltin hydride and azobisisobutyronitrile in an appropriate solvent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5c3bcda9a477a624df02ddd7b98ef12d https://doi.org/10.1016/s0040-4039(00)97480-x Zobrazit plný text záznamu