Intramolecular mobility of polymers with mesogenic groups in the side chains

Autor: A.V. Kharitonov, Ya.S. Freidzon, T.P. Stepanova, T.I. Borisova, L.L. Burshtein, V.P. Shibayev
Rok vydání: 1982
Předmět:
Zdroj: Polymer Science U.S.S.R.. 24:1664-1670
ISSN: 0032-3950
DOI: 10.1016/0032-3950(82)90449-x
Popis: The molecular mobility in dilute solutions of esters of poly-ω-methacryloyloxycarboxylic acids has been investigated. Two relaxation processes involving dipole polarization have been observed in these systems. It has been shown that the process connected with the mobility of end polar groups may be used in analysing the intramolecular structure-formation. The effect of the length of the aliphatic “spacer” and the structure of the end group in the side chain on the intramolecular mobility of the macromolecules has been elucidated.
Databáze: OpenAIRE