Metal Complexes with a New Ethyl Acetate Pendant-Armed Macrocyclic Ligand – Crystal Structures of [MnL](ClO4)2 and [NiL](ClO4)2·CH3CN

Autor:	Paulo Pérez-Lourido, L. Valencia Matarranz, Montserrat López-Deber, R. Bastida de la Calle, Alejandro Macías, Adolfo Rodríguez
Rok vydání:	2007
Předmět:	Stereochemistry Ligand Ethyl acetate Crystal structure Ion Inorganic Chemistry Metal Perchlorate chemistry.chemical_compound chemistry visual_art Polymer chemistry X-ray crystallography visual_art.visual_art_medium Macrocyclic ligand
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 633:1842-1846
ISSN:	1521-3749 0044-2313
DOI:	10.1002/zaac.200700224
Popis:	A new ligand, L, bearing two ethyl acetate pendant groups has been synthesized by reaction of the precursor ligand LA with ethylbromoacetate. The coordination capability towards transition [Mn2+, Ni2+], post-transitional [Zn2+ and Cd2+] and Pb2+ ions has been investigated starting from the hydrated perchlorate salts of the metals. The new ligand L and the metal complexes obtained were characterized by elemental analysis, FAB MS, conductivity measurements, magnetic studies, IR, UV-vis and 1H and 13C NMR spectroscopy. Furthermore, the crystal structures of the complexes [MnL](ClO4)2 and [NiL](ClO4)2·CH3CN were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5c146be08dc1d1cbfbb7a71cfa8230df https://doi.org/10.1002/zaac.200700224 Zobrazit plný text záznamu Plný text