Mechanism of a cobalt(III)-catalyzed olefin hydrosilation reaction: direct evidence for a silyl migration pathway

Autor:	B. E. Grant, M. Brookhart
Rok vydání:	1993
Předmět:	Olefin fiber Silylation Stereochemistry Hydrosilylation chemistry.chemical_element General Chemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry Reaction rate constant chemistry Electrophile Aliphatic compound Cobalt
Zdroj:	Journal of the American Chemical Society. 115:2151-2156
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00059a008
Popis:	The electrophilic Co(III) complex [Cp * (P(OMe) 3 )CoCH 2 CH 2 -μ-H] + BAr' 4 - (1; BAr' 4 - =B[3,5-(CF 3 ) 2 C 6 H 3 ] 4 - has been demonstratcd to be an efficient catalyst for the regiospecific hydrosilation of 1-hexene. The spectroscopic defection of the catalyst resting statc species [Cp * (P(OMe) 3 )CoCH(Bu)CH(SiEt 3 )-μ-H] + (2) in solutions of working catalyst systems has provided direct evidence for a silyl migration pathway
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5c0740b60c0f3b8661a7b63b0f9bfd73 https://doi.org/10.1021/ja00059a008 Zobrazit plný text záznamu