Reactions of manganese π-acetylenic, η-vinylidenic, and η-allenylidenic complexes with Fe2(CO)9. Crystal and molecular structure of Cp(CO)2Mn(μ2-CCHCOOCH3)Fe(CO)4

Autor:	G. G. Aleksandrov, O. S. Zhvanko, Yu. T. Struchkov, L. L. Ivanov, N. E. Kolobova
Rok vydání:	1982
Předmět:	Ligand Stereochemistry Organic Chemistry chemistry.chemical_element Manganese Biochemistry Inorganic Chemistry Crystal Hexane Crystallography chemistry.chemical_compound chemistry Materials Chemistry Molecule Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 228:265-272
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)84327-2
Popis:	The interaction between Cp(CO) 2 Mn(CCHCOOMe) (I), Cp(CO) 2 Mn(π-HCCCOOMe) (II), Cp(CO) 2 Mn(CCCPh 2 ) (III), and Fe 2 (CO) 9 in hexane gives rise to the complexes Cp(CO) 2 Mn(μ 2 -CCHCOOMe)Fe(CO) 4 (IVa,b) and Cp(CO) 2 Mn(μ 2 -CCCPh 2 )Fe(CO) 4 (VIII). The structure of IVb was determined by X-ray analysis. This compound is a binuclear complex with the Fe(CO) 4 and Cp(CO) 2 Mn fragments linked by a FeMn bond and a carbomethoxyvinylidenic ligand. Compound IVa is a geometrical isomer of IVb.
Databáze:	OpenAIRE
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