Acetylation and benzoylation of various aromatics on sulfated zirconia

Autor:	V. Quaschning, H. Lieske, J. Deutsch, Erhard Kemnitz, Annette Trunschke, D. Müller
Rok vydání:	2004
Předmět:	organic chemicals Process Chemistry and Technology Anisole Toluene Catalysis Benzoic anhydride Acylation Acetic anhydride chemistry.chemical_compound Benzoyl chloride chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Mesitylene
Zdroj:	Journal of Molecular Catalysis A: Chemical. 207:51-57
ISSN:	1381-1169
Popis:	Sulfated zirconia (SZ) has been found to have a high performance in the benzoylation of anisole. Thus, several aromatics were reacted with benzoic anhydride, benzoyl chloride, and acetic anhydride as acylating agents on SZ, to give the corresponding benzophenones and acetophenones. The rate of the acylation reactions is dependent on the nature of the respective aromatic. The reactivity decreases in the following order: anisole>mesitylene > 3-chloroanisole ∼ m-xylene ∼ 2-chloroanisole > toluene for benzoylations on SZ. The application of SZ as a catalyst for the acetylation of aromatics was only successful in case of anisole.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5bed803d1a120678c5c4bfa4713af2c2 https://doi.org/10.1016/s1381-1169(03)00471-0 Zobrazit plný text záznamu Full Text from ScienceDirect