Comparison between graphene supported Pt hollow nanospheres and graphene supported Pt solid nanoparticles for hydrogen evolution reaction

Autor: Jahan-Bakhsh Raoof, Roudabeh Valiollahi, Reza Ojani
Rok vydání: 2014
Předmět:
Zdroj: Energy. 74:871-876
ISSN: 0360-5442
DOI: 10.1016/j.energy.2014.07.062
Popis: Platinum hollow nanospheres are synthesized by Co nanoparticles as sacrificial template and then immobilized on graphene nanosheets (HNPt/G). The as-prepared nanostructure is characterized by TEM (transmission electron microscopy) and EDX (energy dispersion X-ray spectroscopy). The prepared HNPt/G is used as electrocatalyst for HER (hydrogen evolution reaction). For this purpose, GC (glassy carbon) electrode modified by HNPt/G was fabricated (HNPt/G/GC). Electrochemical studies show that HNPt/G has a good electrocatalytic activity toward HER. For comparison solid Pt nanoparticles were synthesized and decorated on graphene (NPt/G). The HNPt/G exhibit an enhanced electrocatalytic performance for HER compared with NPt/G.
Databáze: OpenAIRE