Vapor−Liquid Equilibria for Ethanol + Hept-1-yne and Butyric Acid + Butyric Anhydride
Autor: | Yi-Zhi Chu, and Mark Lindrud, David Zudkevitch |
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Rok vydání: | 1999 |
Předmět: | |
Zdroj: | Journal of Chemical & Engineering Data. 44:393-397 |
ISSN: | 1520-5134 0021-9568 |
DOI: | 10.1021/je980210f |
Popis: | Experimental (x, y, P) measurements of ethanol + hept-1-yne at 55 °C and 75 °C and butyric acid + butyric anhydride at 120 °C and 155 °C were obtained in an isothermal circulating glass still. The vapor pressure of hept-1-yne was measured from 43 °C to 100 °C. Ethanol + hept-1-yne exhibits moderate positive deviations from ideal behavior and a minimum-boiling homogeneous azeotrope at both temperatures. Butyric acid + butyric anhydride exhibits weak positive deviations, and no azeotrope was observed. |
Databáze: | OpenAIRE |
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