Vapor−Liquid Equilibria for Ethanol + Hept-1-yne and Butyric Acid + Butyric Anhydride

Autor: Yi-Zhi Chu, and Mark Lindrud, David Zudkevitch
Rok vydání: 1999
Předmět:
Zdroj: Journal of Chemical & Engineering Data. 44:393-397
ISSN: 1520-5134
0021-9568
DOI: 10.1021/je980210f
Popis: Experimental (x, y, P) measurements of ethanol + hept-1-yne at 55 °C and 75 °C and butyric acid + butyric anhydride at 120 °C and 155 °C were obtained in an isothermal circulating glass still. The vapor pressure of hept-1-yne was measured from 43 °C to 100 °C. Ethanol + hept-1-yne exhibits moderate positive deviations from ideal behavior and a minimum-boiling homogeneous azeotrope at both temperatures. Butyric acid + butyric anhydride exhibits weak positive deviations, and no azeotrope was observed.
Databáze: OpenAIRE