Reductive dehydration of alcohols: A route to alkanes

Autor:	N. A. Plate, F. A. Yandieva, Glebov Leonid S, Vladimir G. Zaikin, Alexander E. Gekhman, I. I. Moiseev, Mikaya Anzor I, E. V. Slivinskii, M. V. Tsodikov, V. Ya. Kugel, G. A. Kliger
Rok vydání:	2004
Předmět:	chemistry.chemical_classification Alkane Reaction mechanism chemistry.chemical_element Alcohol General Chemistry Heterogeneous catalysis Aldehyde Catalysis Computer Science Applications chemistry.chemical_compound Hydrocarbon chemistry Modeling and Simulation Organic chemistry Carbon
Zdroj:	Kinetics and Catalysis. 45:854-866
ISSN:	1608-3210 0023-1584
DOI:	10.1007/s10975-005-0050-7
Popis:	The reductive dehydration of cyclic (C5, C6) and aliphatic (C2–C4) alcohols into polycycloalkanes and alkanes whose carbon skeleton has at least twice as many atoms as that of the original substrate is reported for the first time. This reaction takes place at 250–350°C and 7–50 atm in the presence of a polymetallic catalytic system based on an iron-containing fused catalyst or a hydrided iron- and titanium-containing intermetallide mixed with a small amount of Pt/Al2O3. The mechanism of this new reaction is discussed in terms of the mechanisms of known reactions of alcohols and aldehydes enlarging the carbon skeleton.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5b9e8d7261dd973f8f2e5e6225fc0590 https://doi.org/10.1007/s10975-005-0050-7 Zobrazit plný text záznamu Plný text ve formátu PDF