A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters

Autor:	E. V. Zernova, Vahan V. Simonyan, V. M. Mamaev, Andrew V. Prisyajnyuk, Igor P. Gloriozov, Yurii A. Ustynyuk
Rok vydání:	1997
Předmět:	Degenerate energy levels chemistry.chemical_element General Chemistry Oxidative phosphorylation Photochemistry Oxidative addition Potential energy symbols.namesake chemistry Chemical physics Intramolecular force Cluster (physics) symbols Hamiltonian (quantum mechanics) Palladium
Zdroj:	Mendeleev Communications. 7:246-248
ISSN:	0959-9436
DOI:	10.1070/mc1997v007n06abeh000801
Popis:	The mechanism of dihydrogen oxidative addition to the simplest palladium cluster has been analysed within the framework of the reaction-path Hamiltonian approximation; a planar dihydride complex has been found to form without the potential energy barrier and intramolecular degenerate exchange of the protons in the complex has been investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5b7e7392178f6e939fdc99e51fd14c12 https://doi.org/10.1070/mc1997v007n06abeh000801 Zobrazit plný text záznamu Full Text from ScienceDirect