Study of the spatial structure of the chloroanhydride of dichloromethylphosphonic acid by a combination of various physical methods

Autor:	A. V. Aganov, M. M. Gilyazov, F. G. Khalitov, O. A. Raevskii, I. A. Safin, N. G. Mumzhieva, D. U. Zakirov
Rok vydání:	1976
Předmět:	Orientation (vector space) Dichloromethylphosphonic acid Crystallography Liquid state chemistry Group (periodic table) Spatial structure Intramolecular force Chlorine chemistry.chemical_element General Chemistry Conformational isomerism
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:2514-2519
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00920890
Popis:	1. In the liquid state, in solution, and in one of its crystalline modifications, the chlorohydrate of dichloromethylphosphonic acid exists as a mixture of two nonrotating isomers of Cs and C1 symmetries (gauche-gauche and gauche-trans orientation of the two CHCl2 group chlorines with respect to the P=O bond). The conformers are individually stabilized in the other crystalline modifications. 2. It is assumed that weak intramolecular bonds of the C-H...O=P type play a role in the stabilizing the conformer with the chlorine in the gauche-trans orientation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5b7df7b4ba0533ca8ca6a72686d5ccb1 https://doi.org/10.1007/bf00920890 Zobrazit plný text záznamu Full text from SpringerLink