Organotin Selenocarboxylates: Synthesis and Some Reactions

Autor:	Toyohiko Endo, Mutsuaki Komada, Hideharu Ishihara, Shinya Muto, Shinzi Kato
Rok vydání:	1989
Předmět:	chemistry.chemical_compound Aluminium chloride chemistry Benzyl bromide Moisture Bromide Organic Chemistry medicine chemistry.chemical_element Organic chemistry Oxygen Catalysis medicine.drug
Zdroj:	Synthesis. 1989:929-932
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-1989-27432
Popis:	A series of di- 3 and triorganotin esters 2 of aromatic selenocarboxylic acid were synthesized and characterized. The organotin esters 2 and 3 are stable thermally, but labile towards moisture and oxygen. They readily reacted with benzyl bromide in the presence of aluminium chloride to afford benzyl selenocarboxylates 4 in moderate yields. The reaction of triphenyltin selenocarboxylates with phenylselenenyl bromide led to acyl phenyl diselenides 5 in good yields
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5b7afc84a714af71ff5340b59f040d3e https://doi.org/10.1055/s-1989-27432 Zobrazit plný text záznamu