Study of Reactions between Fluoro-substituted Nucleogenic Phenyl Cations and Benzopyridine Derivatives

Autor:	Roman V. Shchepin, Sergey N. Shurov, V. V. Avrorin, N. E. Shchepina, Gennadii A. Badun
Rok vydání:	2020
Předmět:	Nucleogenic Nitrogen atom Chemistry Heteroatom chemistry.chemical_element Physical and Theoretical Chemistry 010402 general chemistry 010403 inorganic & nuclear chemistry Ring (chemistry) 01 natural sciences Medicinal chemistry Nitrogen 0104 chemical sciences
Zdroj:	Radiochemistry. 62:101-106
ISSN:	1608-3288 1066-3622
DOI:	10.1134/s1066362220010130
Popis:	A study of ion-molecular reactions of fluoro-substituted phenyl cations with benzopyridine derivatives demonstrated the following: (a) at present only the nuclear-chemical method enables the reaction of a direct phenylation of the nitrogen atom in benzopyridine derivatives, which makes it possible to obtain previously unknown quaternized structures, and (b) generation of nucleogenic phenyl cations with various substituents leads to a simultaneous introduction of the required substituents into the aromatic ring at the nitrogen heteroatom. Quantum-chemical calculations additionally confirmed the assumption about the pathways of the ion-molecular reactions with nucleogenic phenyl cations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5b781dfd321e7c38507aade3bf8669a2 https://doi.org/10.1134/s1066362220010130 Zobrazit plný text záznamu Full text from SpringerLink