ChemInform Abstract: Novel Ring Transformation of Mesoionic Oxazoles into 2(1H)-Pyrazinones by the Reaction with TosMIC

Autor:	Masami Kawase, Hidemitsu Uno, Ryosuke Saijo, Kazuki Akira, Ken-ichi Kurihara
Rok vydání:	2013
Předmět:	chemistry.chemical_compound Transformation (genetics) chemistry TosMIC Mesoionic chemistry.chemical_element Organic chemistry General Medicine Molecular oxygen Ring (chemistry) Combinatorial chemistry Oxygen
Zdroj:	ChemInform. 44
ISSN:	0931-7597
Popis:	Treatment of mesoionic 1,3-oxazolium-5-olates with TosMIC in the presence of a base causes a novel ring transformation affording 2(1H)-pyrazinones in moderate yields. The origin of C-2 carbonyl oxygen in the product was elucidated to be molecular oxygen, based on 18O-labeling experiments.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5b4941c46ddd3e7e7283a8f73bf84b6f https://doi.org/10.1002/chin.201347166 Zobrazit plný text záznamu Plný text