| Autor: |
Yuh-Lin Mao, Tzuen-Yeuan Lin, Chih-Ming Chuo |
| Rok vydání: |
1991 |
| Předmět: |
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| Zdroj: |
Journal of the Chinese Chemical Society. 38:167-170 |
| ISSN: |
0009-4536 |
| Popis: |
The kinetics of chromic acid oxidation of glyoxal is reported. The reaction is first-order in glyoxal and indicates a gradual change from a first-order to a zero-order dependence on acidity. The kinetic nature of this reaction has been studied and the rate law is consistent with a proposed mechanism as follows; rate = kKb, K[Cr+6][Gx][H+]/(l+0.238[H+]) at 25°C. The product analysis indicates that formic acid is the oxidation product under similar kinetic condition. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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