Reaction of tetrakis(trifluoromethyl)allene with [?5-C5H5Mo(CO)3]? and [?5-C5H5W(CO)3]?

Autor:	M. Ya. Solodova, I. B. Zlotina, N. E. Kolobova
Rok vydání:	1977
Předmět:	chemistry.chemical_compound Trifluoromethyl chemistry Allene General Chemistry Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2168-2170
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00923645
Popis:	1. The reaction of tetrakis(trifluoromethyl)allene with [η5-C5H5W(CO)3]− gives the σ-complex, which when heated is converted to the π-allylidene complex. 2. The reaction of tetrakis(trifluoromethyl)allene with [η5-C5H5Mo(CO)3]− leads to the formation of the π-allylidene complex.
Databáze:	OpenAIRE
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