Insights into the Origin of Water Soluble Organic Carbon in Atmospheric Fine Particulate Matter

Autor: James J. Schauer, David C. Snyder, Chris Worley, Andrew P. Rutter, Ryan J Collins
Rok vydání: 2009
Předmět:
Zdroj: Aerosol Science and Technology. 43:1099-1107
ISSN: 1521-7388
0278-6826
Popis: Concentrations of fine carbonaceous aerosols (PM 2.5 ), including elemental carbon (EC), organic carbon (OC), and water-soluble organic carbon (WSOC) were measured from filters collected every 6th day for one year at three urban/industrial sites in the Midwestern United States: Cincinnati, Cleveland, and Mingo Junction, Ohio. The water-soluble fraction of fine particulate OC varied considerably from site to site and monthly averages were between 39–85% at Cincinnati, 35–68% at Cleveland, and 32–65% at Mingo Junction. Average monthly concentrations of WSOC were compared with measurements of organic source tracers, including levoglucosan, to better understand the spatial and temporal distribution and sources of WSOC. Two methods of predicting the non-biomass burning portion of WSOC (WSOC NB ) were compared including estimation of secondary organic carbon (SOC) by the EC-tracer Method and comparison of the unapportioned OC from a chemical mass balance (CMB) source apportionment analysis. Poor correlations be...
Databáze: OpenAIRE