ChemInform Abstract: Selective and Efficient Access to ortho, meta and para Ring- Substituted Phenylacetylene Derivatives R-(CC-C6H4)x-Y (Y: H, NO2, CN, I, NH2)

Autor: Sandrine Cabioch, Pierre H. Dixneuf, Jiri Vohlidal, Olivier Lavastre
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 28
ISSN: 0931-7597
DOI: 10.1002/chin.199739095
Popis: ortho, meta and para isomers of iodo and amino ring-substituted phenylacetylene as well as rod-like arylacetylene derivatives were prepared by a simple synthetic route involving three consecutive reactions: the palladium-catalysed carbon-carbon bond formation, the Sandmeyer reaction and the desilylation of the protected trimethylsilylalkynes.
Databáze: OpenAIRE