The lycoctonine family of alkaloids: a stereochemical revision

Autor:	O. E. Edwards, M. Przybylska
Rok vydání:	1982
Předmět:	Group (periodic table) Stereochemistry Chemistry Organic Chemistry General Chemistry Lycoctonine Catalysis
Zdroj:	Canadian Journal of Chemistry. 60:2661-2667
ISSN:	1480-3291 0008-4042
Popis:	A redetermination of the structure of des(oxymethylene)lycoctonine hydriodide has shown that a wrong choice had been made between the real and false mirror image peaks for the atoms of the 1-methoxyl group in the original pseudosymmetric Fourier synthesis. It has been demonstrated that lycoctonine samples from many sources are identical, and that no rearrangement took place in forming des(oxymethylene)lycoctonine. Hence all alkaloids that have been related to lycoctonine have a 1α-methoxyl group.
Databáze:	OpenAIRE
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