Acceptor substituted N-heterocyclic carbenes and their Rh(I)complexes: Synthesis, structure and properties
| Autor: | Eberhardt Herdtweck, Wolfgang A. Herrmann, Stephan D. Hoffmann, Peter Härter, Agnes Bittermann |
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| Rok vydání: | 2008 |
| Předmět: |
Tolman electronic parameter
Organic Chemistry Thermal decomposition Infrared spectroscopy chemistry.chemical_element Photochemistry Biochemistry Acceptor Adduct Rhodium Inorganic Chemistry chemistry.chemical_compound Transmetalation chemistry Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Carbene |
| Zdroj: | Journal of Organometallic Chemistry. 693:2079-2090 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2008.01.039 |
| Popis: | Rhodium(I) complexes of acceptor substituted N-heterocyclic carbenes were obtained either by transmetalation from the corresponding Ag(I) complexes or by thermal decomposition of corresponding pentafluorobenzene carbene adducts. All complexes were fully characterized by means of NMR- and mass spectroscopy. Compounds 5, 6, 7 and 11 were although characterized by single-crystal X-ray analysis. The relative σ-donor/π-acceptor strength of the NHC ligands was determined by means of IR spectroscopy. Dimerisation behaviour of Rh carbonyl complexes was studied. |
| Databáze: | OpenAIRE |
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