Derivatives of titanium with compounds having bidentate ligands

Autor:	D.M. Puri, K. C. Pande, Ram C. Mehrotra
Rok vydání:	1962
Předmět:	Chemistry Inorganic chemistry General Engineering chemistry.chemical_element Chloride Nitrobenzene chemistry.chemical_compound Monomer Alkoxide Polymer chemistry Anhydrous medicine Titanium tetrachloride Hydrogen chloride medicine.drug Titanium
Zdroj:	Journal of the Less Common Metals. 4:481-486
ISSN:	0022-5088
Popis:	The preparation of titanium dichloride diacetylacetone (TiCl2(acac)2) from titanium tetrachloride and titanium dichloride dialkoxide is described. It has been shown that the compound can be obtained by the reaction between titanium dialkoxide diacetylacetone and hydrogen chloride, whereas it is converted into the alkoxide derivative by the reaction with alcohol in presence of anhydrous ammonia. These reactions together with low conductivities in nitrobenzene confirm the simple monomeric formulation TiCl2(acac)2. The preparation of titanium trichloride monoacetylacetone has been described and its reactions and those of the dichloride derivative, with alcohols and acids have been studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5abe545b8e98acd204907f4dde8c5241 https://doi.org/10.1016/0022-5088(62)90035-8 Zobrazit plný text záznamu