Oxidation of Benzylic Alcohols with Urea Hydrogen Peroxide/Calcium Chloride in PEGDME250

Autor: Su Jeong Ha, Eun-Young Jung, Jong Chan Lee, Received August, Won Mi Kim
Rok vydání: 2014
Předmět:
Zdroj: Bulletin of the Korean Chemical Society. 35:629-630
ISSN: 0253-2964
DOI: 10.5012/bkcs.2014.35.2.629
Popis: However, most of the aforementionedreagent systems are generally exotic, toxic, and expensivewhich limit their practical applications. In addition, hydro-gen peroxide is considered to be an ideal green oxidant forthe oxidation reactions of alcohol s due to its low toxicity andready availability. However, utilization of hydrogen peroxidefor the alcohol oxidation reactions generally required use oftransition metal based peroxo-complexes as activators.
Databáze: OpenAIRE