A novel synthesis of 10-aryl-9-arsaanthracenes

Autor:	F.M. Bickelhaupt, C. Jongsma, R.J.M. Weustink
Rok vydání:	1977
Předmět:	chemistry.chemical_compound Flash vacuum pyrolysis Chemistry Yield (chemistry) Aryl Organic chemistry General Chemistry
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 96:265-270
ISSN:	0165-0513
DOI:	10.1002/recl.19770961007
Popis:	10-Aryl-9-arsaanthracenes (3b,c,d) were conveniently synthesized by flash vacuum pyrolysis at ∼ 500° of 10-mono- and di-substituted 9-aryl-9,10-dihydro-9-arsaanthracenes (11a-f). The yield of 10-aryl-9-arsaanthracenes is found to depend upon the substituents at C(10). The occurrence of radical intermediates is discussed briefly.
Databáze:	OpenAIRE
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