Autor:	László Rákos, Christina Moberg, Louise Tottie
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Stereospecificity chemistry Nucleophile Styrene oxide Yield (chemistry) Oxide Organic chemistry Regioselectivity General Medicine Lewis acids and bases Catalysis
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199243076
Popis:	The methanolysis of (R)-styrene oxide catalyzed by SnCl4 has been found to proceed with complete regioselectivity with nucleophilic attack at the benzylic position, and with inversion of configuration at the benzylic carbon as the predominant stereochemical course, affording (S)-2-methoxy-2-phenylethanol (95% ee) in high yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5a645d3340568e2307433bdb60af4f58 https://doi.org/10.1002/chin.199243076 Zobrazit plný text záznamu Plný text