ChemInform Abstract: Reaction of Perfluoro-2-methylpent-2-ene and Perfluoro-5-azanon-4-ene with Aniline and Its Derivatives

Autor:	Georgii G. Furin, Irina Yu. Bagryanskay, Ki-Whan Chi, Yurii V. Gatilov
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Aniline chemistry Pentafluoroaniline Quinoline Organic chemistry General Medicine Carbon-13 NMR Spectral data Medicinal chemistry Ene reaction
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200040042
Popis:	Reaction of perfluoro-2-methylpent-2-ene ( 1 ) and perfluoro-5-azanon-4-ene ( 2 ) with aniline, 4-fluoroaniline, 4-methoxyaniline and 2,6-dimethylaniline in the presence of Et 3 N provides derivatives of quinoline and quinozaline, whereas reaction of 2 yields diazetine derivatives with 2- and 4-nitroanilines, 2,6-dichloroaniline and pentafluoroaniline. The structure of [2-(1,1,2,2,3,3,3-pentafluoroethyl)-3-trifluoromethyl-quinoline-4-yl]-phenylamine is confirmed by X-ray structural data. The routes of reactions and the 19 F and 13 C NMR spectral data of the products are discussed.
Databáze:	OpenAIRE
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