Reactions of Molybdenum(V)porphyrins with Phenol Derivatives Involving Parallel Inner and Outer Sphere Electron Transfer

Autor:	Yoshihisa Matsuda, Masato Kurihara, Yoko Morinaga, Ikuko Saito
Rok vydání:	1997
Předmět:	Absorption spectroscopy Ligand chemistry.chemical_element General Chemistry Inner sphere electron transfer Photochemistry Porphyrin Metal chemistry.chemical_compound Electron transfer chemistry Molybdenum visual_art visual_art.visual_art_medium Outer sphere electron transfer
Zdroj:	Chemistry Letters. 26:17-18
ISSN:	1348-0715 0366-7022
Popis:	Reactions of oxoethoxomolybdenum(V)porphyrins and substituted phenols were investigated by UV-vis absorption spectra. Ligand substitution or reduction of the metal center proceeded depending on the steric repulsion between the substituents of the phenols and the porphyrin skeletons. Proton transfer from the phenols to the axial ligand of the molybdenumporphyrin initiated the reactions. Parallel outer sphere and inner electron transfer proceeded parallel in the reduction of the molybdenum center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5a55ba2c01ed1cbddcb4ad3a26b91b13 https://doi.org/10.1246/cl.1997.17 Zobrazit plný text záznamu