Cesium doping to improve the electrochemical performance of layered Li1.2Ni0.13Co0.13Mn0.54O2 cathode material
| Autor: | Yi-Xuan Li, Shuo Wang, Yasmin Aqsa, Xiang Ding, Chunhua Chen, Qiao Hu, Miao-Miao Deng |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Mechanical Engineering Doping Metals and Alloys 02 engineering and technology Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Cathode 0104 chemical sciences law.invention Chemical engineering Mechanics of Materials law Electrode Materials Chemistry Calcination 0210 nano-technology High-resolution transmission electron microscopy Faraday efficiency |
| Zdroj: | Journal of Alloys and Compounds. 791:100-108 |
| ISSN: | 0925-8388 |
| DOI: | 10.1016/j.jallcom.2019.03.297 |
| Popis: | Aiming to improve the rate capability and cycling stability, cesium doped Li-rich cathode materials Li1.2-xCsxNi0.13Co0.13Mn0.54O2 (x = 0, 0.012, 0.036, 0.060, 0.096) are synthesized by a sol-gel method and a subsequent calcination process. The optimal Cs+ content is found to be x = 0.060. After Cesium doping to Li+ sites, the enlarged interplanar spacing of (003) plane, which is confirmed by high resolution transmission electron microscopy, can accelerate the Li+ diffusion during the lithiation/delithiation process at the interface of electrode/electrolyte. The obtained Cs-doped Li-rich sample with x = 0.060 exhibits much improved electrochemical performance compared with the bare, especially the rate capability (148 mAh g−1 compared to 50 mAh g−1 at 10 C). The first discharge capacity is much enhanced from 250 to 281 mAh g−1 at 0.1 C with a heightened coulombic efficiency from 72% to 81%. XRD, SEM, TEM, elemental mapping, EDS and ICP-AES are adopted to characterize the morphologies and structures. |
| Databáze: | OpenAIRE |
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