Molecular complexes of group 13 element trihalides, pentafluorophenyl derivatives and Lewis superacids

Autor:	T. N. Sevastianova, Alexey Y. Timoshkin, E. I. Davydova
Rok vydání:	2015
Předmět:	Boron group Chemistry Stereochemistry Intermolecular force NacNac Medicinal chemistry Acceptor Inorganic Chemistry chemistry.chemical_compound Group (periodic table) Materials Chemistry Moiety Lewis acids and bases Physical and Theoretical Chemistry Bifunctional
Zdroj:	Coordination Chemistry Reviews. :91-126
ISSN:	0010-8545
DOI:	10.1016/j.ccr.2015.02.019
Popis:	In the present review recent advances in the chemistry of group 13 Lewis acids, such as intermolecular complexes with donor–acceptor metal–metal bonds, bifunctional Lewis acids and complexes of Lewis superacids, as well as selected examples of their application in different areas of chemistry are presented. Structural properties of molecular donor–acceptor complexes formed by strong group 13 element Lewis acids EX3 (E = B, Al, Ga; X = Cl, C6F5) with M,C,N,P,O,S-donor-ligands (M – main group or transition metal) are presented and changes in the geometry of the acceptor moiety upon complex formation are analyzed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::59f6126383540fbee895d41ba66a19fb https://doi.org/10.1016/j.ccr.2015.02.019 Zobrazit plný text záznamu Full Text from ScienceDirect