NMR study of localization and mobility of 1-phenylethanol enantiomers in homochiral metal-organic sorbent Zn2 (bdc)(S -lac)(dmf)

Autor:	Maxim P. Yutkin, Marsel R. Gallyamov, Svetlana G. Kozlova, Svyatoslav P. Gabuda, N. K. Moroz
Rok vydání:	2015
Předmět:	Metal Sorbent Chemistry Chemical shift visual_art visual_art.visual_art_medium Molecule Organic chemistry General Materials Science General Chemistry Enantiomer Carbon-13 NMR Medicinal chemistry
Zdroj:	Magnetic Resonance in Chemistry. 53:578-581
ISSN:	0749-1581
DOI:	10.1002/mrc.4262
Popis:	Structural features of localization of chiral isomers of 1-phenylethanol (R-PhEtOH and S-PhEtOH) and their mobility activation in homochiral metal-organic [Zn2 (bdc)(S-lac)(dmf)] sorbent were studied with (1)H and (13)C NMR methods. (13)C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S-PhEtOH and R-PhEtOH clearly indicates that stabilization of [Zn2(bdc)(S-lac)(dmf)]·S-PhEtOH structure is more preferable than stabilization of [Zn2 (bdc)(S-lac)(dmf)]·R-PhEtOH structure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::59d217d79f298b785182ff66d5a7a7c2 https://doi.org/10.1002/mrc.4262 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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