Reaction of Arylazo Aryl Sulfone with Olefins in the Presence of Tetrakis(triphenylphosphine)palladium(0)

Autor:	Takeshi Satoh, Nobumasa Kamigata, Michio Kobayashi, Tetsuya Kondoh, Masayuki Kameyama
Rok vydání:	1987
Předmět:	Aryl chemistry.chemical_element General Chemistry Tetrakis(triphenylphosphine)palladium(0) Medicinal chemistry Catalysis Sulfone Styrene Adduct chemistry.chemical_compound chemistry Organic chemistry Triphenylphosphine Palladium
Zdroj:	Chemistry Letters. 16:347-350
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1987.347
Popis:	Catalytic reaction of arylazo aryl sulfone with olefins in the presence of tetrakis(triphenylphosphine)palladium(0) was investigated. Arylation of olefins was the major product, and 1:1 adduct of arylazo and arenesulfonyl group to olefins was obtained as minor product. Diarylpalladium(II) species was proposed as an intermediate in this reaction.
Databáze:	OpenAIRE
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