REACTIONS PARTICULIERES DE CYANO ALKYLE SULFURES APPLICATION A L'OBTENTION DE DERIVES ACRYLIQUES

Autor:	J. L. Mieloszynski, Y. Jullien, J. Y. Melwig, Daniel Paquer, M. Curci, J. C. Wilhelm
Rok vydání:	1996
Předmět:	Inorganic Chemistry chemistry.chemical_classification chemistry.chemical_compound chemistry Double bond Sulfonium Organic Chemistry Organic chemistry Sulfoxide Reactivity (chemistry) Biochemistry Medicinal chemistry Alkyl
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 118:95-104
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509608038803
Popis:	The reactivity of Ph-SH with acrylic compounds permits a protection of the acrylic double bond and reaction on the protected product. In some cases (cyano alkyl acrylic compounds) a specific reaction can be observed. So action of KCN on PhS-(CH2)2-COO-(CH2)aCl [n = 2,3] gives NC-(CH2)2-COO-(CH2)a SPh [the expected compound (PhS-(CH2)2-COO-(CH2)aCN) was not isolated]. We involve a sulfonium ion as intermediate for this ‘abnormal’ reaction. When n = 6 the normal protection/deprotection reaction occurs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::59cb7fc84ac0089578a0bf97d3fbcc6b https://doi.org/10.1080/10426509608038803 Zobrazit plný text záznamu