Quantum chemical study of the mechanism of the Claisen amino rearrangement

Autor:	Z. N. Saraeva, O. A. Ponomarev, Abdrakhmanov Ildus B, Tolstikov Genrikh A, N. G. Nigmatullin, B. G. Zykov
Rok vydání:	1991
Předmět:	Quantum chemical Linear combination of atomic orbitals Chemistry Computational chemistry Stereochemistry MNDO General Chemistry Sigmatropic reaction Carroll rearrangement Mechanism (sociology) Cope rearrangement
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:552-556
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00957994
Popis:	Using the LCAO MO method in the MNDO approximation, we have compared the concerted [3, 3]-sigmatropic and stepwise mechanisms for the acid-catalyzed Claisen amino rearrangement. The latter is preferred.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::59c9f55a6e31ca34d569765b2fe71909 https://doi.org/10.1007/bf00957994 Zobrazit plný text záznamu Full text from SpringerLink