ChemInform Abstract: Palladium on Charcoal Catalyzed 3,4-Hydroperoxidation of α-Substituted Enals with Triethylsilane and Water

Autor:	Petri M. Pihko, Sakari Tuokko
Rok vydání:	2016
Předmět:	chemistry.chemical_classification Autoxidation chemistry.chemical_element General Medicine Transfer hydrogenation Aldehyde Catalysis chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Organic chemistry Triethylsilane Charcoal Conjugate Palladium
Zdroj:	ChemInform. 47
ISSN:	0931-7597
Popis:	Aldehyde α-hydroperoxides can be accessed from α-substituted acroleins with triethylsilane and water under Pd/C catalysis and aerobic conditions. The reaction is composed of a Pd/C-catalyzed conjugate reduction step and a hydroperoxidation step. The hydroperoxidation takes place via autoxidation of sufficiently stable enols formed in situ by transfer hydrogenation. Upon reduction, 2,2-disubstituted 1,2-diols are obtained directly from aldehydes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::59c17523a36d17980ca6cd2a2993703b https://doi.org/10.1002/chin.201646058 Zobrazit plný text záznamu Plný text