Darstellung und Molekülstruktur von Bis(3-dimethylaminopropylalan)

Autor:	Karl-Heinz Thiele, Joachim Sieler, Ulf Dümichen, Thomas Gelbrich
Rok vydání:	1995
Předmět:	Inorganic Chemistry NMR spectra database Crystallography Chemistry Aluminium Intramolecular force Organic Chemistry X-ray crystallography Materials Chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 495:71-75
ISSN:	0022-328X
DOI:	10.1016/0022-328x(95)05418-o
Popis:	Me 2 NCH 2 CH 2 CH 2 Li reacts with AlCl 3 with formation of Cl 2 AlCH 2 CH 2 CH 2 NMe 2 II which can be transferred into Bis(3-dimethylaminopropylalane), [H 2 AlCH 2 CH 2 CH 2 NMe 2 ] 2 III by means of LiH. III can be obtained also by intramolecular hydroalumination reaction of the complex H 3 Al → NMe 2 CH 2 CHCH 2 IV . MS, 1 H, 13 C and 27 Al NMR spectra and the X-ray structure of III are reported and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::59b31fa3934f4f144a19fae22ac21c82 https://doi.org/10.1016/0022-328x(95)05418-o Zobrazit plný text záznamu Full Text from ScienceDirect