Synthesis of С(3)–С(8) eleutheside blocks from levoglucosenone

Autor:	A. N. Davydova, B. T. Sharipov, Farid A. Valeev
Rok vydání:	2020
Předmět:	chemistry.chemical_compound Primary (chemistry) 010405 organic chemistry Chemistry Organic Chemistry Hydroxy group Aromatization 010402 general chemistry Ring (chemistry) 01 natural sciences Medicinal chemistry 0104 chemical sciences
Zdroj:	Chemistry of Heterocyclic Compounds. 56:982-989
ISSN:	1573-8353 0009-3122
DOI:	10.1007/s10593-020-02764-8
Popis:	The synthesis of stable chiral C(3)–C(8) eleutheside blocks with the corresponding substituents was carried out on the basis of levoglucosenone. This synthetic method eliminates the possibility of aromatization of intermediate and final products to furans due to the formation of the 2,5-dihydrofuran ring at the final steps and the involvement of derivatives protected at the primary hydroxy group in the ring formation reaction.
Databáze:	OpenAIRE
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