Fourfold C–H Borylation of Anthracene: 1,3,5,7-Tetraborylanthracene and Its Application to 1,3,5,7-Tetraarylanthracenes

Autor:	Kenji Yoza, Kenji Kobayashi, Yuta Takaki
Rok vydání:	2017
Předmět:	Anthracene chemistry.chemical_compound chemistry 010405 organic chemistry Solid-state General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Borylation Fluorescence 0104 chemical sciences Catalysis
Zdroj:	Chemistry Letters. 46:655-658
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.170037
Popis:	Iridium-catalyzed direct tetraborylation of anthracene to give 1,3,5,7-tetrakis(Bpin)anthracene 5 was achieved by using a combination of [Ir(OMe)(COD)]2 and tmphen as the catalyst. Compound 5 was applied to the synthesis of 1,3,5,7-tetraarylanthracenes 7 as a new molecular entity. The latter showed long fluorescence lifetime in the solid state.
Databáze:	OpenAIRE
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