Synthesis of EuS and EuSe particles via thermal decomposition of dithio- and diselenophosphinate europium complexes
| Autor: | Alexey N. Konev, M. E. Burin, Georgy K. Fukin, Mikhail N. Bochkarev, Anatoly P. Pushkarev, R. V. Rumyantsev |
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| Rok vydání: | 2017 |
| Předmět: |
Diffraction
Lanthanide Photoluminescence Thermal decomposition Inorganic chemistry General Engineering chemistry.chemical_element Nanoparticle 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Colloid chemistry Physical chemistry General Materials Science 0210 nano-technology Europium Luminescence |
| Zdroj: | Nanotechnologies in Russia. 12:66-72 |
| ISSN: | 1995-0799 1995-0780 |
| DOI: | 10.1134/s1995078017010025 |
| Popis: | New two- and trivalent europium complexes with dithio- and diselenodiphenylphosphinate ligands (S2PPh 2 - and Se2PPh 2 - ) have been synthesized as precursors for nanoparticles. Two-valent europium compounds have been characterized via X-ray diffraction. Their photoluminescence properties have been studied as well. EuS colloidal nanoparticles have been obtained via the thermolysis of Eu(S2PPh2) n (n = 2, 3) in a hexadecylamine medium at 310°C. The average size of objects is found to be 40–70 nm. As is established, the valent state of a lanthanide in the complex exerts no influence on the size of the forming nanoparticles or on the luminescence spectrum of colloidal solutions. |
| Databáze: | OpenAIRE |
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