Aryl(alkyl)hydrosilanes in reactions with m-nitrostyrene

Autor:	L. M. Tartakovskaya, V. V. Nepomnina, A. I. Anpilogova, V. I. Sidorov, K. S. Pushchevaya, K. A. Andrianov
Rok vydání:	1971
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Addition reaction Hydrogen Chemistry Hydride Aryl Organic chemistry chemistry.chemical_element General Chemistry Medicinal chemistry Alkyl
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 20:1037-1039
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00862226
Popis:	1. When a study was made of the reaction of the dimethylphenyl-, diphenylmethyl-, and triphenylsilanes with m-nitrostyrene in the presence of H2PtCl6 it was established that dimethylphenylsilane is most inclined to undergo the hydride addition reaction; the reaction for the reduction of m-nitrostyrene to m-aminostyrene is characteristic for triphenylsilane; diphenylmethylsilane occupies an intermediate position. 2. In the reactions of the dimethylphenyl- and diphenylmethylsilanes with m-nitrostyrene the hydrogen of the Si-H bond adds in the β-position of the C=C bond of the latter.
Databáze:	OpenAIRE
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