Diffusion of Isotope Tracers in Binary Liquid Solutions

Autor: W. Reimschüssel, E. Hawlicka, S. Karolczak
Rok vydání: 1980
Předmět:
Zdroj: Berichte der Bunsengesellschaft für physikalische Chemie. 84:227-231
ISSN: 0005-9021
DOI: 10.1002/bbpc.19800840306
Popis: The behaviour of isotope tracers in diffusion processes was investigated. In systems of organic binary solutions gradients of chemical concentration were present. Using the capillary method the tracer and the mutual diffusion coefficients were determined. It was found that the tracer diffusion coefficient is equal to the mutual one if the tracer moves in the same directions as the unlabelled part of component and the ratio of both parts of component is time independent. When both conditions are not justified the tracer diffusion is due to the simultaneously mutual and self-diffusion processes.
Databáze: OpenAIRE