Physical Properties of Vegetable Oil and Chlorinated Ethene Mixtures
| Autor: | Angela R. Bielefeldt, Patricia Pfeiffer, Tissa H. Illangasekare, Bruce Henry |
|---|---|
| Rok vydání: | 2005 |
| Předmět: |
Environmental Engineering
Chromatography food.ingredient Chemistry Mole fraction Soybean oil Physical property Viscosity food Chemical engineering Volume (thermodynamics) Phase (matter) Volume fraction Environmental Chemistry Dissolution General Environmental Science Civil and Structural Engineering |
| Zdroj: | Journal of Environmental Engineering. 131:1447-1452 |
| ISSN: | 1943-7870 0733-9372 |
| DOI: | 10.1061/(asce)0733-9372(2005)131:10(1447) |
| Popis: | Laboratory experiments were conducted to investigate the abiotic interactions of soybean oil (SoyOil) and chlorinated ethene (CE) nonaqueous phase liquids (NAPLs). The mixed NAPL density and interfacial tension behaved ideally, as predicted by the volume ratio. The mixed NAPL viscosity increased exponentially from that of the pure CE to that of pure SoyOil as the volume fraction increased. The measured contact angle was highly variable and was unpredictable as a function of the volume composition of the mixed NAPL. The physical property effects indicate that the mobilization of residual CE NAPLs because of SoyOil injection is unlikely. Equilibrium dissolution of CEs from the NAPL mixtures behaved linearly as a function of the mole fraction. Dissolved SoyOil in simulated groundwater enhanced the dissolution of trichloroethene (TCE) during flow tests, increasing the effluent TCE concentration from 141 to 202 mg∕L . The ready intermingling of the CE dense nonaqueous phase liquids (DNAPLs) and SoyOil indicate... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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