Gold-Catalyzed Benzannulation of Electronically Rich/Rich and Deficient/Deficient Oxoalkynes with Alkynes

Autor:	Tarun K. Sarkar, Biswajit Panda
Rok vydání:	2013
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Pyridine Homogeneous catalysis Alcohol Lewis acids and bases Combinatorial chemistry Catalysis Cycloaddition
Zdroj:	Synthesis. 45:1227-1234
ISSN:	1437-210X 0039-7881
Popis:	Two different strategies have been developed to perform the gold-catalyzed benzannulation of both electron-rich pyridine containing oxoalkynes with electron-rich alkynes as well as electron-deficient pyridine containing oxoalkynes with electron-deficient­ alkynes. The benzannulation between electron-rich oxoalkynes with electron-rich alkynes proceeds in the presence of highly electron-deficient gold catalysts, whereas using catalytic amount of alcohol benzannulation was performed efficiently between electron-deficient oxoalkynes with electron-deficient alkynes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::591361594ad4ac95dd93ebd771eda143 https://doi.org/10.1055/s-0032-1318454 Zobrazit plný text záznamu