Preparation and characterization of p-type Sb2Te3 and n-type Bi2Te3 thin films grown by coevaporation

Autor: D. M. Rowe, Helin Zou, Gao Min
Rok vydání: 2001
Předmět:
Zdroj: Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 19:899-903
ISSN: 1520-8559
0734-2101
DOI: 10.1116/1.1354600
Popis: p-type antimony telluride thin films and n-type bismuth telluride thin films have been deposited by coevaporation on glass substrates. The conditions for deposition have been investigated as a function of substrate temperature (Ts), flux ratio (Fr=F(Te)/F(Sb, Bi)) and optimized to achieve a high thermoelectric power factor. The quality of deposited films, e.g. structure, composition and morphology, has been examined by x-ray diffraction, energy dispersive x-ray analysis, flame atomic absorption spectroscopy, and with an atomic force microscope. The thermoelectric properties of the thin films have been evaluated by room temperature measurement of the Seebeck coefficient, Hall coefficient, and electrical resistivity. Both the crystallinity and the transport properties are strongly affected by nonstoichiometry with the highly stoichiometric samples exhibiting a high crystallinity and high thermoelectric power factor. The Seebeck coefficient and electrical conductivity of p-type Sb2Te3 thin film (αp, σp) and ...
Databáze: OpenAIRE