When phosphoryl azide meets mechanochemistry: clean, rapid, and efficient synthesis of phosphoryl amides under B(C6F5)3 catalysis in a ball mill

Autor:	Xin-Hua Peng, Zhuo Li, Ze-Lin Wang, Lin-Yu Jiao, Nan Jia
Rok vydání:	2021
Předmět:	chemistry.chemical_compound chemistry Nucleophile Mechanochemistry Reagent Phosphorus chemistry.chemical_element Azide Combinatorial chemistry Ball mill Catalysis
Zdroj:	Catalysis Science & Technology. 11:6659-6665
ISSN:	2044-4761 2044-4753
DOI:	10.1039/d1cy01314a
Popis:	We described herein the first example associated with B(C6F5)3-catalyzed preparation of phosphoryl amides under mechanochemical conditions. In this novel system, the combination of energetic reagents with an energetic mechanochemical process enabled the reaction to proceed under very mild conditions and accelerated the desired nucleophilic attack on the phosphorus center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::58ed148f849f84177d42feff73549711 https://doi.org/10.1039/d1cy01314a Zobrazit plný text záznamu