Ph[PhC(O)NH]2PNC(O)Ph: a new mesomeric stabilized azaylide. Synthesis, crystal structure and IR spectroscopic results

Autor:	Alfred Kolbe, Lothar Jäger, C. Wagner, T. Saplinova
Rok vydání:	2004
Předmět:	Chemistry Hydrogen bond Organic Chemistry Inorganic chemistry Solid-state Infrared spectroscopy Crystal structure Analytical Chemistry Inorganic Chemistry Crystallography symbols.namesake symbols Raman spectroscopy Spectroscopy
Zdroj:	Journal of Molecular Structure. 690:25-29
ISSN:	0022-2860
Popis:	The structure of Ph[PhC(O)NH]2PNC(O)Ph (2) in solid state and in solution is discussed on the basis of a crystal structure analysis and IR and Raman spectra. In crystalline state 2 forms dimers which are associated via two pairs of bifurcated (N–H)2⋯OC hydrogen bonds. The spectroscopic data are in good agreement with the crystallographic results with respect to the hydrogen bonding and they suggest that 2 also in solution is associated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::58e15c4fe1aa0527f045042b1f0a3b02 https://doi.org/10.1016/j.molstruc.2003.10.048 Zobrazit plný text záznamu Full Text from ScienceDirect